Martensitic steel grades and precipitation hardening (PH) stainless steels are heat treatable

and can therefore provide hardness and strength in a wide range of applications.

Allowing to workability they are supplied in solution annealed condition.

The downstream manufacturer performs final heat treatment to meet the mechanical properties required.
Martensitic stainless steel grades are basically Fe-Cr alloys with a higher carbon content than ferritics

which enables them to harden on cooling in air, oil or water.

Depending on grade and intended use, ductility is improved by tempering.

What is martensitic stainless steel?
High strength and hardness distinguish martensitic stainless steels from the other stainless steel families.

After austenitizing cooling is performed in air, water or oil, depending on steel grade.

If the intended application requires a high level of hardness (e.g. knives, HRC55),

only stress relief annealing will be performed. Normally martensitic stainless steels are tempered

in order to acquire useful mechanical properties, i.e. a certain level of toughness (A5 ≥ 15 %).

Typical applications for martensitic stainless steel grades:

• cutting utensils
• surgical and dental Instruments
• fasteners, springs and ball bearings
• press plates
• steam and gas turbines
• Limited weldability

Traditional martensitic steels with a carbon content > 0.20 % are difficult to weld; assistance is advised.

The hardenable high-carbon grades are not suitable for welding.

Low-carbon nickel-martensitic steel grades have relatively good weldability.

Welding of precipitation hardened stainless steel grades is possible,

but depending on grade some limitations might have to be regarded.

Varying corrosion resistance
Corrosion resistance of martensitic stainless steels may vary considerably depending on

chemical composition (C, Cr, Mo), surface finish and especially heat treatment.

Smooth polished surfaces experience higher resistance than rougher finishes.

In terms of heat treatment the hardened condition is more favourable, since the elements promoting

corrosion resistance are in solution and therewith effective.

Tempering may lead to carbide precipitation which impairs corrosion resistance.

This is always the case for traditional martensitic grades, whereas nickel-martensitic grades with

max 0.06 % carbon and 3-6 % nickel (e.g. EN 1.4313 and EN 1.4418) do not sacrifice corrosion resistance by tempering.

Corrosion resistance of precipitation hardening steels is higher compared with heat treatable martensitic stainless steels ranking between ferritic Cr and austenitic CrNi steels.

What is precipitation hardening stainless steel?
Precipitation hardening stainless steels provide remarkable levels of high strength and hardness in a very wide range.

With the exception of the martensitic alloys (e.g. 17-4PH / EN 1.4542) cold formability is satisfactory.

Precipitation hardening grades have higher alloying contents than martensitic steel grades.

They contain nickel, and in order to achieve hardening by aging additions of copper, aluminium,

titanium, niobium and molybdenum.

Depending on chemical composition their microstructure after final heat treatment is austenitic, semi-austenitic or martensitic.

Typical applications for precipitation hardening grades:

• retaining rings, spring holders, springs
• chains, valves and gears
• aircraft parts
• pressure vessels and seals